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You searched for: subject:"second-order effects"
[movies]MIT 5.80 Small-Molecule Spectroscopy and Dynamics, Fall 2008 - MIT OpenCourseWare
The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbatio...
Keywords: spectroscopy; harmonic oscillators; matrix; hamiltonian; heisenberg; vibrating rotor; Born-Oppenheimer; diatomics; laser schemes; angular momentum; hund's cases; energy levels; second-order effects; perturbations; Wigner-Eckart; Rydberg-Klein-Rees; rigid rotor; asymmetric rotor; vibronic coupling; wavepackets
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